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Preparation and anisotropic mechanical behavior of highly‐oriented electrospun poly(butylene terephthalate) fibers
Author(s) -
Mathew G.,
Hong J. P.,
Rhee J. M.,
Leo D. J.,
Nah C.
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.23762
Subject(s) - materials science , composite material , anisotropy , electrospinning , ultimate tensile strength , drum , fiber , orientation (vector space) , polymer , geometry , mechanical engineering , optics , mathematics , physics , engineering
This work describes the effect of the speed of drum‐type rotating collector in an electrospinning process on the orientation of electrospun poly(butylene terephthalate) fiber mats, and its effect on the tensile properties. The degree of orientation increased with the increase in the drum speed (surface velocity) up to a critical level, and thereafter, wavy fibers were observed. The average diameter reduced and its distribution became narrower with increase in the velocity. The mechanical properties in a parallel direction improved about three times with increase in the surface velocity. The anisotropic mechanical behavior could be predicted with a simple classical equation. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2017–2021, 2006

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