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Hydroxyalkylation of parabanic acid. III. Polymers from parabanic acid and ethylene carbonate
Author(s) -
ZarzykaNiemiec Iwona,
Naróg Dorota,
Lubczak Jacek
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.23506
Subject(s) - imide , polymer chemistry , polymer , catalysis , ethylene , ethylene carbonate , reagent , carbonate , materials science , molar ratio , chemistry , organic chemistry , electrolyte , electrode
The influence of initial molar ratio of reagents, amount of catalyst, and temperature of reaction between parabanic acid and ethylene carbonate on structure of product was studied. The reaction led to the opening of the trioxoimidazolidine ring, resulting in formation of thermally resistant linear polymeric products constructed of urea and oxoamidoester subunits linked via imide bond. The percentage of side products was estimated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1443–1449, 2006