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Miscibility in binary blends of aromatic and alicyclic polyamides
Author(s) -
Endo Masahiro,
Morishima Yasuyuki,
Yano Shinichi,
Tadano Kenji,
Murata Yukinobu,
Tsunashima Kenji
Publication year - 2006
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.22912
Subject(s) - miscibility , isophthalic acid , adipic acid , polyamide , materials science , terephthalic acid , copolymer , cyclohexane , polymer chemistry , alicyclic compound , differential scanning calorimetry , diamine , chemistry , polymer , organic chemistry , composite material , polyester , physics , thermodynamics
Miscibility was studied for four polyamide blends of 6I/6T [copolymer consisting of 1,6‐hexamethylene diamine and isophthalic acid (6I) (70 wt %) and terephthalic acid (6T) (30 wt %)] with MXD6 (polyamide of m ‐xylenediamine and adipic acid), BAC6 (polyamide of 1,3‐bis(aminomethyl)cyclohexane and adipic acid), TR55 (copolymer consisting of nylon 11 (30 wt %), and polyamide of bis(3‐methyl, 4‐aminocyclohexyl)methane (30 wt %) and isophthalic acid (70 wt %), and CX7323 (polyamide of bis(4‐aminocyclohexyl)methane and dodecanedicarboxylic acid), using differential scanning calorimetry, X‐ray diffraction method, and electronmicroscopic observation. In quenched MXD6/(6I/6T) and BAC6/(6I/6T) blends, MXD6 and BAC6 components were miscible to 6I/6T, but TR55 and CX7323 components were completely phase‐separated from 6I/6T. Interestingly on electronmicroscopic observations, TR55 and CX7323 components were seen as droplets in 6I/6T medium when the content is low, but when 50 wt %, a layered structure was constructed with 6I/6T, reminiscent of morphological structure in block copolymer. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3971–3978, 2006