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The synthesis and application of Pb‐doped GLYMO/chelated‐zirconium complex coating materials for UV‐light absorption
Author(s) -
Asiltürk Meltem,
Sayılkan Funda,
Sayılkan Hikmet,
İçduygu Galip
Publication year - 2005
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.22583
Subject(s) - zirconium , materials science , coating , absorption (acoustics) , fourier transform infrared spectroscopy , sol gel , absorption spectroscopy , visible spectrum , nuclear chemistry , analytical chemistry (journal) , silane , ultraviolet visible spectroscopy , doping , chemical engineering , chemistry , organic chemistry , optics , nanotechnology , composite material , metallurgy , optoelectronics , physics , engineering
New glass coating materials containing γ‐glycidoxypropyltrimethoxy‐silane/zirconium(IV)‐ n ‐propoxide(2‐methoxyethylacetoacetate)/lead(II) nitrate were developed for UV‐light absorption by sol‐gel process. The effect of agitation time, temperature, and Zr complex and Pb 2+ ion concentrations on UV light absorption were investigated. Zr complex was characterized by using 1 H‐NMR, 13 C‐NMR, and FTIR spectroscopy. Ultraviolet visible spectroscopy was utilized to determine the optical properties of coating materials. Results showed that coated glass has very low transmission in the UV region (300–400 nm) relative to uncoated glass, especially at 150°C for 15 h agitation. UV light transmission of coated glasses treated at 80, 100, 450, or 500°C was not different from uncoated glass. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1175–1179, 2006