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Synthesis and characterization of a poly(ether–ester) copolymer from poly(2,6 dimethyl‐1,4‐phenylene oxide) and poly(ethylene terephthalate)
Author(s) -
GarcíaGaitán B.,
PérezGonzález M. del P.,
ZárateAcevedo M. C.,
MartínezRicha A.,
LunaBárcenas G.,
NuñoDonlucas S. M.
Publication year - 2005
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.22539
Subject(s) - copolymer , polymer chemistry , phenylene , ether , dimethyl terephthalate , materials science , ethylene oxide , glass transition , polymerization , condensation polymer , fourier transform infrared spectroscopy , monomer , chemistry , organic chemistry , polyester , polymer , chemical engineering , engineering , composite material
A series of poly(ether–ester) copolymers were synthesized from poly(2,6 dimethyl‐1,4‐phenylene oxide) (PPO) and poly(ethylene terephthalate) (PET). The synthesis was carried out by two‐step solution polymerization process. PET oligomers were synthesized via glycolysis and subsequently used in the copolymerization reaction. FTIR spectroscopy analysis shows the coexistence of spectral contributions of PPO and PET on the spectra of their ether–ester copolymers. The composition of the poly(ether–ester)s was calculated via 1 H NMR spectroscopy. A single glass transition temperature was detected for all synthesized poly(ether–ester)s. T g behavior as a function of poly(ether–ester) composition is well represented by the Gordon‐Taylor equation. The molar masses of the copolymers synthesized were calculated by viscosimetry. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006

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