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Anisotropic network formation by the photopolymerization of new monomers derived from 4‐hydroxybenzenethiol
Author(s) -
Sáez P.,
Aguilera C.
Publication year - 2005
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.21936
Subject(s) - photopolymer , monomer , mesophase , materials science , polyimide , liquid crystal , dichroism , polymer chemistry , anisotropy , chemical engineering , composite material , polymer , optics , layer (electronics) , optoelectronics , physics , engineering
New polymerizable difunctional liquid crystals of monomers derived from 4‐hydroxybenzenethiol were synthesized, characterized, and photopolymerized by the formation of anisotropic films. These films were obtained by the irradiation of the monomers in the mesophase with UV light before they were macroscopically oriented in glasses treated on the surface with polyimide and uniaxially rubbed. The monomers showed smectic and nematic mesophases. The thin films, uniaxially oriented, were optically transparent. The orientation was verified by IR dichroism, which showed a preferential order of mesogens. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1812–1817, 2005