Poly( N ‐phenylmaleimide‐ co ‐β‐methyl hydrogen itaconate): Synthesis, characterization, and copper(II)‐ion‐binding properties | Zendy

Pizarro Guadalupe del C. | Zendy; Marambio Oscar G. | Zendy; JeriaOrell Manuel | Zendy; Huerta Margarita R. | Zendy; Rivas Bernabé L. | Zendy

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Poly( N ‐phenylmaleimide‐ co ‐β‐methyl hydrogen itaconate): Synthesis, characterization, and copper(II)‐ion‐binding properties

Author(s) -

Pizarro Guadalupe del C.,

Marambio Oscar G.,

JeriaOrell Manuel,

Huerta Margarita R.,

Rivas Bernabé L.

Publication year - 2005

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.21359

Subject(s) - copolymer , polymer chemistry , monomer , reactivity (psychology) , fourier transform infrared spectroscopy , copper , hydrogen , materials science , chemistry , polymer , organic chemistry , chemical engineering , medicine , alternative medicine , pathology , engineering , composite material , metallurgy

The radical copolymerization of N ‐phenylmaleimide was carried out with β‐methyl hydrogen itaconate at 70°C for 12 h. The copolymers were characterized by elemental analysis, thermal analysis, Fourier transform infrared, and 1 H‐NMR spectroscopy. The monomer reactivity ratios were determined by the Kelen–Tüdös and Fineman–Ross methods. These values demonstrated that the copolymerization reaction produced statistical copolymers with a tendency to alternation. The retention capacity of the copolymers for Cu 2+ ions varied from 296 to 348 mg/g at pHs 5 and 7. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1361–1367, 2005

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