Poly(amide‐ester)s derived from dicarboxylic acid and aminoalcohol | Zendy

Borriello Anna | Zendy; Nicolais Luigi | Zendy; Huang Samuel J. | Zendy

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Poly(amide‐ester)s derived from dicarboxylic acid and aminoalcohol

Author(s) -

Borriello Anna,

Nicolais Luigi,

Huang Samuel J.

Publication year - 2004

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.21270

Subject(s) - condensation polymer , thermal stability , amide , glass transition , polymer chemistry , polymer , melting point , inherent viscosity , materials science , fourier transform infrared spectroscopy , thermal decomposition , dicarboxylic acid , intrinsic viscosity , atmospheric temperature range , chemistry , chemical engineering , organic chemistry , composite material , thermodynamics , physics , engineering

A series of alternating aliphatic poly(amide‐ester)s, derived from dicarboxylic acid and aminoalcohols, were obtained by polycondensation in melt. All poly(amide‐ester)s were characterized by FTIR and 1 H/ 13 C‐NMR spectroscopies. The synthesized polymers showed an inherent viscosity ranging from 0.4 to 1.0 dL g −1 . Thermal analysis showed melting points within the range 100–115°C and glass transition within the range 30–60°C. Decomposition temperatures were more than 200°C higher than the corresponding melting temperatures. The polymers can thus be processed from the melt. The processed polymers were partially crystalline with good thermal stability. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 362–368, 2005

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