Premium
Mechanical and thermal properties of poly(lactic acid)/starch blends with dioctyl maleate
Author(s) -
Zhang JianFeng,
Sun Xiuzhi
Publication year - 2004
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.21078
Subject(s) - plasticizer , ultimate tensile strength , materials science , absorption of water , starch , compatibilization , lactic acid , polymer blend , aqueous solution , chemical engineering , polymer chemistry , composite material , chemistry , organic chemistry , polymer , copolymer , biology , bacteria , engineering , genetics
Poly(lactic acid) (PLA)/starch blends were prepared blending with dioctyl maleate (DOM). DOM acted as a compatibilizer at low concentrations (below 5%), and markedly improved tensile strength of the blend. However, DOM functioned as a plasticizer at concentrations over 5%, significantly enhancing elongation. Compatibilization and plasticization took place simultaneously according to the analysis of, for example, mechanical properties and thermal behavior. With DOM as a polymeric plasticizer, thermal loss in the blends was not significant. Water absorption of PLA/starch blends increased with DOM concentration. DOM leaching in an aqueous environment was inhibited. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1697–1704, 2004