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Soluble and conductive copolymers from 1‐(hydroxyalkyl) pyrroles
Author(s) -
Kişkan Bariş,
Akar Ahmet,
Kızılcan Nilgün,
Ustamehmetoğlu Belkıs
Publication year - 2005
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.21069
Subject(s) - copolymer , pyrrole , polymer chemistry , hydroxymethyl , polymerization , fourier transform infrared spectroscopy , chemistry , proton nmr , materials science , organic chemistry , polymer , chemical engineering , engineering
Abstract 1‐Substituted pyrroles such as 1‐(hydroxymethyl)pyrrole, 1‐(3‐hydroxypropyl) pyrrole, 1‐ H ‐1‐pyrrolylmethyl 4‐methyl‐1‐benzenesulfonate, 1‐ H ‐1‐pyrrolylpropyl 4‐methyl‐1‐benzenesulfonate, and 1‐ H ‐pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH 4 ) 2 Ce(NO 3 ) 6 and FeCl 3 . Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, 1 H‐NMR, and four‐point probe conductivity. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1830–1834, 2005