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Toughening of polypropylene–ethylene copolymer with nanosized CaCO 3 and styrene–butadiene–styrene
Author(s) -
Chen Jianfeng,
Wang Guoquan,
Zeng Xiaofei,
Zhao Hongying,
Cao Dapeng,
Yun Jimmy,
Tan Chee King
Publication year - 2004
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.20925
Subject(s) - materials science , polypropylene , composite material , copolymer , nanocomposite , toughness , polymer , izod impact strength test , extrusion , compounding , styrene , nanoparticle , particle size , acrylonitrile butadiene styrene , particle (ecology) , phase (matter) , chemical engineering , ultimate tensile strength , nanotechnology , chemistry , organic chemistry , engineering , oceanography , geology
Nanocomposites of nanosized CaCO 3 /polypropylene–ethylene copolymer (PPE) and nanosized CaCO 3 /PPE/styrene–butadiene–styrene (SBS) were prepared by using a two‐roll mill and a single‐screw extruder. By adding CaCO 3 nanoparticles into the PPE matrix, the toughness of the matrix substantially improved. At a nanosized CaCO 3 content of 12 phr (parts per hundred PPE resin by weight), the impact strength of CaCO 3 /PPE at room temperature reached 61.6 kJ/m 2 , which is 3.02 times that of unfilled PPE matrix. In the nanosized CaCO 3 /PPE/SBS system, the rubbery phase and filler phase are independently dispersed in the PPE matrix. As a result of the addition of nanosized CaCO 3 , the viscosity of PPE matrix significantly increased. The increased shear force during compounding continuously breaks down SBS particles, resulting in the reduction of the SBS particle size and improving the dispersion of SBS in the polymer matrix. Thus the toughening effect of SBS on matrix was improved. Simultaneously, the existence of SBS provides the matrix with a good intrinsic toughness, satisfying the condition that nanosized inorganic particles of CaCO 3 efficiently toughen the polymer matrix. The synergistic toughening function of nanosized CaCO 3 and SBS on PPE matrix was exhibited. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 796–802, 2004