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Hydroxyalkylation of parabanic acid. II. Reactions of parabanic acid with oxiranes
Author(s) -
ZarzykaNiemiec Iwona,
Lubczak Jacek
Publication year - 2004
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.20907
Subject(s) - epichlorohydrin , propylene oxide , ethylene oxide , reagent , catalysis , polymer chemistry , oxide , molar ratio , organic chemistry , materials science , chemistry , ring (chemistry) , copolymer , polymer
Reactions of parabanic acid with ethylene oxide, propylene oxide, or glycerin epichlorohydrin were studied at the initial molar ratios of reagent ranging from 1 : 1 to 1 : 8. The effects of catalyst presence and temperature on the course of reaction were analyzed. The conditions were established at which the parabanic acid ring was preserved and those at which it opened to form polymeric products. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 317–326, 2004