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Thermally stable conducting composites based on a carbon black‐filled polyoxadiazole matrix
Author(s) -
Souza Fernando G.,
Sena Maria E.,
Soares Bluma G.
Publication year - 2004
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.20601
Subject(s) - carbon black , materials science , composite material , electrical resistivity and conductivity , percolation threshold , thermal stability , composite number , percolation (cognitive psychology) , conductivity , carbon fibers , epoxy , thermal conductivity , ambient pressure , chemical engineering , chemistry , physics , natural rubber , neuroscience , electrical engineering , biology , engineering , thermodynamics
New thermally stable conducting materials can be obtained by dispersing conducting carbon black into poly(4,4′‐diphenylether‐1,3,4‐oxadiazole) (POD–DPE) solution in NMP. The blend preparation process resulted in quite good dispersed composite and a relatively low percolation threshold (around 5 wt % of CB). The effect of the compressive stress on the resistivity of composite has been evaluated. The resistivity decreases continuously as the applied pressure is increased. In addition to the electrical conductivity, the presence of carbon black resulted in higher thermally stable materials. The thermal stability, electrical conductivity, and pressure‐sensible characteristics make this conducting material a good candidate for application in manufacture of pressure sensors for high temperature ambient. This material shows a typical semiconductor behavior, characterized by an increase of conductivity with the temperature. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1631–1637, 2004