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Ion‐conducting polymer gels of polyacrylamide embedded with K 2 CO 3
Author(s) -
Song Wensheng,
Wang Yuxin,
Deng Huining
Publication year - 2004
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.20118
Subject(s) - polymer , polyacrylamide , polymerization , membrane , materials science , self healing hydrogels , ionic conductivity , electrolyte , chemical engineering , ionic bonding , monomer , polymer chemistry , scanning electron microscope , ionic strength , fourier transform infrared spectroscopy , ion , chemistry , composite material , aqueous solution , organic chemistry , electrode , biochemistry , engineering
A highly ionic conductive solid‐gel membrane based on polyacrylamide hydrogels with a K 2 CO 3 additive was investigated. The polymer‐based gel was prepared by adding ionic species K 2 CO 3 to a monomer solution followed by polymerization. After polymerization, the ionic species was embedded in the polymer‐based gel, where it remained. The ionic species behaved like a liquid electrolyte, whereas the polymer‐based solid‐gel membrane provided a smooth impenetrable surface that allowed for the exchange of ions. The gel membranes were obtained in the form of thin films of reasonable mechanical strength. Their ambient temperature conductivities were in the range 10 −2 to 10 −1 S/cm. The effect of K 2 CO 3 concentration on the conductivity of the gels prepared was examined in the temperature range from 0 to 100°C. The microstructure and chemical composition of the gels studied were characterized by environmental scanning electron microscopy and FTIR, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2076–2081, 2004