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Monitoring water uptake of polyurethanes by in situ fluorescence technique
Author(s) -
Hakala K.,
Vatanparast R.,
Vuorimaa E.,
Lemmetyinen H.
Publication year - 2001
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1998
Subject(s) - fluorescence , polyurethane , gravimetric analysis , in situ , polymer , materials science , analytical chemistry (journal) , adhesive , chemistry , polymer chemistry , composite material , chromatography , organic chemistry , optics , physics , layer (electronics)
The water uptake of three polyurethane adhesives was studied by an in situ fluorescence method applying extrinsic fluorescent probes. The measurements were made in water immersion at 50 and 80°C, and in water vapor at 50°C. An intensity ratio method was applied, in which ratios of the highest and lowest intensity changes in the fluorescence emission bands were used to determine the amount of water sorbed in the polymer films. The ratio method was used to compare the fluorescence data with those obtained by a conventional gravimetric method. Comparable results were obtained. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1593–1599, 2001