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Preparation and characterization of cellulose acetate organic/inorganic hybrid films
Author(s) -
Shojaie Saeed S.,
Rials Timothy G.,
Kelley Stephen S.
Publication year - 1995
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1995.070580807
Subject(s) - tetraethyl orthosilicate , sol gel , cellulose , cellulose acetate , materials science , chemical engineering , phase (matter) , solvent , organic component , hybrid material , polymer chemistry , chemistry , organic chemistry , nanotechnology , engineering
A series of organic/inorganic hybrid (OIH) films were prepared using cellulose acetate (CA) as the organic component and tetraethyl orthosilicate (TEOS) as the inorganic component. The chemical, morphological, and mechanical properties of these films were evaluated with a variety of analytical techniques. The results of these evaluations showed that crosslinked CA OIH films were formed during the sol‐gel reactions. The structure of OIH films was very sensitive to the CA/TEOS ratio and film formation conditions. All of the films with added TEOS were two phase on a molecular level, i.e., inorganic TEOS domains surrounded by a CA matrix. Under some film formation conditions the presence of TEOS, a nonsolvent for CA, led to solvent/nonsolvent phase separation on the micron scale. © 1995 John Wiley & Sons, Inc.