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Poly(vinyl chloride)/styrene‐butadiene rubber blends prepared by dynamic vulcanization with nitrile rubber as the compatibilizer
Author(s) -
Zhu S.H.,
Chan C.M.,
Zhang Y. X.
Publication year - 1995
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1995.070580317
Subject(s) - vulcanization , materials science , curing (chemistry) , plasticizer , nitrile rubber , vinyl chloride , natural rubber , thermoplastic elastomer , composite material , polyvinyl chloride , elastomer , phthalate , styrene butadiene , styrene , polymer chemistry , polymer , copolymer
A new kind of thermoplastic elastomer is obtained by dynamic curing of PVC/SBR blends. A compatibilizer is necessary, and of three tested—NBR and two ABSs—NBR‐18 is the best. Sulfur and Dicumyl peroxide were chosen as the two different curing agents for the blends. The curing agent and its concentration have a dramatic effect on the mechanical properties. Di(2‐ethyl hexyl)phthalate was used as the plasticizer for PVC. Variations in the PVC and di(2‐ethyl hexyl)phthalate concentrations can produce materials having a wide range of hardness and strength to meet the needs of different applications. The effects of processing parameters such as blending time and processing temperature and the effect of filler in the blend on the mechanical properties were also investigated. The material, after processing five times, showed no significant changes in physical properties. © 1995 John Wiley & Sons, Inc.