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Determination of interfacial tension between PA/PP and LCP/PP by IFR method and effect of compatibilization on interfacial tension
Author(s) -
Kirjava J.,
Rundqvist T.,
HolstiMiettinen R.,
Heino M.,
Vainio T.
Publication year - 1995
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1995.070550710
Subject(s) - thermotropic crystal , surface tension , materials science , compatibilization , polypropylene , polyamide , polymer , tension (geology) , composite material , polymer blend , polymer science , polymer chemistry , thermodynamics , liquid crystalline , copolymer , ultimate tensile strength , physics
The dynamic imbedded fiber retraction (IFR) method was used to measure the interfacial tension between two molten polymers. The aim was to evaluate the applicability of this method for polypropylene (PP) used as matrix, and two polyamide (PA6, PA66) and thermotropic main‐chain liquid crystalline polymer fibers. The effect on the interfacial properties of modifying the PP matrix with compatibilizers was studied as well. The IFR method was found to be suitable for evaluating the interfacial properties of these polymer blends. The measured interfacial tensions correlated well with the morphology and mechanical properties of the blends and values calculated from the harmonic mean equation. Although the measured interfacial tensions were generally lower than the theoretical ones, the order of the values for the different polymer pairs was similar. © 1995 John Wiley & Sons, Inc.