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A novel TLCP blended with PET and PC matrices
Author(s) -
Joslin Scott,
Jackson Woodward,
Farris Richard
Publication year - 1994
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1994.070540303
Subject(s) - thermotropic crystal , materials science , modulus , composite material , fiber , polycarbonate , synthetic fiber , matrix (chemical analysis) , polymer , liquid crystalline
This investigation focused on the potential of improving the performance of poly(ethylene terephthalate) (PET) and polycarbonate (PC) fibers by incorporating a novel thermotropic liquid crystalline copolymer (TLCP). The degree of mechanical enhancement obtained in the fibers incorporating 20 wt % TLCP depended upon the chosen matrix material and the processing conditions. The PET matrix systems did not exhibit any modulus improvements until after posttreatment of the fibers. Following posttreatment, the blends exhibited a modulus of 24 GPa, an increase of 40% compared to the PET control fiber. The PC systems exhibited a 1 GPa modulus increase in the as‐spun fiber blends, but improvement was negligible after fiber posttreatment. The morphologies of the as‐spun and posttreated fibers suggest that different mechanisms of reinforcement are occurring depending upon the matrix material selected. © 1994 John Wiley & Sons, Inc.