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Gamma‐sterilization effects and influence of the molecular weight distribution on the postirradiation resistance of polypropylene for medical devices
Author(s) -
Martakis Nick,
Niaounakis Michael,
Pissimissis Dimitris
Publication year - 1994
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1994.070510214
Subject(s) - polypropylene , sterilization (economics) , tacticity , materials science , irradiation , molar mass distribution , polymer chemistry , rheology , oxygen , peroxide , dose rate , analytical chemistry (journal) , chemistry , polymer , composite material , radiochemistry , polymerization , organic chemistry , physics , nuclear physics , monetary economics , economics , foreign exchange market , foreign exchange
In the present study, the dose‐rate effects of γ‐irradiation in air on two isotactic polypropylene grades of different molecular weight distribution, used for medical devices, were investigated. The thermal, mechanical, rheological, and photometric properties of these materials were examined using DSC, stress–strain measurements, MFI, and a yellow index. At low dose rates (0.12 Mrad/h), the oxygen diffusion parameter prevailed. At high dose rates (2.84 Mrad/h), the thermal degradation became dominant. However, at high dose rates, an increase in sample temperature was monitored. This temperature rise is thought to increase the oxygen diffusion rate, peroxide decomposition, and radical migration. As a result, intermediate dose rates (in the region of 0.72 Mrad/h) gave the lowest changes in physical properties in both samples. Furthermore, it was found that the polypropylene grade of broader molecular weight distribution and lower M n had a higher γ‐irradiation and postirradiation resistance. © 1994 John Wiley & Sons, Inc.