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Statistical estimation of diffusion coefficients under finite bath, surface barrier conditions
Author(s) -
Etters J. N.
Publication year - 1993
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1993.070490709
Subject(s) - dimensionless quantity , diffusion , computation , thermodynamics , surface (topology) , materials science , chemistry , mechanics , mathematics , physics , geometry , algorithm
When surface‐barrier effects are not taken into account, computation of diffusion coefficients from data obtained under finite bath conditions can lead to error. A technique is given by which the most probable diffusion coefficient and the most probable dimensionless surface barrier parameter simultaneously can be estimated for diffusant uptake by solid polymeric cylinders. © 1993 John Wiley & Sons, Inc.
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