Aqueous ring‐opening metathesis polymerization of  exo ‐7‐oxabicyclo [2.2.1] hept‐5‐ene‐2,3‐dicarboximide | Zendy

Viswanathan Tito | Zendy; Jethmalani Jagdish | Zendy

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Aqueous ring‐opening metathesis polymerization of exo ‐7‐oxabicyclo [2.2.1] hept‐5‐ene‐2,3‐dicarboximide

Author(s) -

Viswanathan Tito,

Jethmalani Jagdish

Publication year - 1993

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.1993.070480717

Subject(s) - polymer chemistry , polymerization , aqueous solution , metathesis , ene reaction , ring opening metathesis polymerisation , chemistry , maleimide , grubbs' catalyst , ring opening polymerization , imide , adduct , furan , polymer , organic chemistry

The aqueous ring‐opening metathesis polymerization of the exo ‐Diels‐Alder adduct of furan and maleimide was accomplished using an “activated Ruthenium” catalyst present in the supernatant of a RuCl 3 ‐catalyzed aqueous polymerization of furan‐dimethylacetylene dicarboxylate adduct. The polymer was characterized by solution 1 H− and 13 C‐NMR, IR, DSC, and viscometry. Characterization revealed an intact imide group and the possibility of high‐temperature applications. © 1993 John Wiley & Sons, Inc.

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