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Photopolymerization of methyl methacrylate using benzoin isopropyl ether as photoinitiator: Effect of thiophenol compounds
Author(s) -
Wang W.,
Hu G. H.
Publication year - 1993
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1993.070470914
Subject(s) - thiophenol , polymerization , chemistry , polymer chemistry , photoinitiator , benzoin , photopolymer , methyl methacrylate , induction period , photochemistry , monomer , organic chemistry , polymer , catalysis
Effects of a series of thiophenols R ArSH with substituting groups R in the para ‐position and 2‐mercaptobenzoic acid on the kinetics of polymerization of methyl methacrylate (MMA) photoinitiated by benzoin isopropyl ether (BIPE) were investigated using an autorecording dilatometer. Thiophenols were found to have a dual effect on polymerization: reducing induction time and accelerating rate of polymerization. A mechanism was proposed suggesting that this increased rate of polymerization and reduced induction time with addition of a thiophenol is due to the fact that, instead of consuming radicals, the dissolved oxygen in the MMA/BIPE system can be converted into active radicals through effective photooxidation of the thiophenol. Although the maximum increase in rate of polymerization is of a minor difference between various thiophenol compounds, reduction in induction time is strongly dependent on the nature of substituting groups in the following order: CH 3 > CH(CH 3 ) 2 > OCH 3 or Cl > H. 2‐Mercaptobenzoic acid, on the other hand, increases induction time and decreases rate of polymerization. © 1993 John Wiley & Sons, Inc.