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Preparation of polymer‐supported schiff base iron (III) complexes and their catalytic activity for decomposition of hydrogen peroxide
Author(s) -
Wang Xin,
Gu Weihong,
Lu Lude,
Chen Zhijin,
Stevens John G.
Publication year - 1992
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1992.070450607
Subject(s) - hydrogen peroxide , salicylaldehyde , schiff base , catalysis , divinylbenzene , copolymer , styrene , polymer chemistry , chemistry , decomposition , polymer , condensation , condensation reaction , inorganic chemistry , organic chemistry , physics , thermodynamics
Polymeric substrates containing salicylidenimine ligands as discrete units can be obtained by reacting chloromethylated divinylbenzene styrene copolymer with amines, followed by condensation with salicylaldehyde. Polymer‐supported Schiff base iron (III) complexes have been prepared and their IR spectra and Mössbauer spectra measured. Catalytic activity of supported complexes have been tested using decomposition of hydrogen peroxide as a model reaction.