Polymerization of  N ‐vinylcarbazole by gaseous initiators | Zendy

Bhadani Suraj N. | Zendy; Gupta Sumanta K. Sen | Zendy; Sinha Arvind K. | Zendy

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Polymerization of N ‐vinylcarbazole by gaseous initiators

Author(s) -

Bhadani Suraj N.,

Gupta Sumanta K. Sen,

Sinha Arvind K.

Publication year - 1992

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.1992.070440119

Subject(s) - polymerization , chain growth polymerization , ionic polymerization , kinetics , polymer chemistry , cationic polymerization , chemistry , chain transfer , dichloroethane , materials science , radical polymerization , polymer , organic chemistry , catalysis , physics , quantum mechanics

The polymerization of N ‐vinylcarbazole initiated with NO 2 and SO 2 in dichloroethane has been studied. The kinetics of polymerization were followed gravimetrically. The Polymerization is fast with NO 2 but a relatively slow rate was obtained with SO 2 . The polymerization with these gases appears to be initiated by a charge transfer mechanism.

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