Electrochemical polymerization of acrylonitrile with quaternary salts | Zendy

Bhadani Suraj N. | Zendy; Ansari Qayumuddin | Zendy; Gupta Sumanta K. Sen | Zendy

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Electrochemical polymerization of acrylonitrile with quaternary salts

Author(s) -

Bhadani Suraj N.,

Ansari Qayumuddin,

Gupta Sumanta K. Sen

Publication year - 1992

Publication title -

journal of applied polymer science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.575

H-Index - 166

eISSN - 1097-4628

pISSN - 0021-8995

DOI - 10.1002/app.1992.070440112

Subject(s) - acrylonitrile , polyacrylonitrile , polymerization , polymer chemistry , monomer , bromide , chemistry , electrochemistry , dimethylformamide , materials science , inorganic chemistry , electrode , organic chemistry , polymer , solvent , copolymer

The electrochemical polymerization of acrylonitrile was carried out in the solutions of tetrabutylammonium bromide and tetrabutylphosphonium bromide in N , N ‐dimethylformamide in a divided electrolytic cell. The formation of polyacrylonitrile of high molecular weight (7.6 × 10 4 ) took place in the cathode compartment. The kinetics of the polymerization was investigated for different initial monomer concentrations, current levels, and electrode materials. The polymerization mechanism is anionic.

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