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Solution process of suspension poly(vinyl chloride) in cyclohexanone by means of a viscometer
Author(s) -
Szewczyk Pawel,
Gruszka Marianna,
Bortel Krzysztof
Publication year - 1991
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1991.070430415
Subject(s) - viscometer , vinyl chloride , cyclohexanone , suspension (topology) , polyvinyl chloride , intrinsic viscosity , dissolution , viscosity , polymer chemistry , polymer , materials science , glass transition , relative viscosity , reduced viscosity , vinyl polymer , macromolecule , chemical engineering , analytical chemistry (journal) , thermodynamics , chemistry , chromatography , organic chemistry , composite material , copolymer , biochemistry , catalysis , mathematics , physics , homotopy , pure mathematics , engineering
To study the structure of grains of suspension poly(vinyl chloride) (PVC), the authors applied a capillary viscometer for cyclic measurements of viscosity of the PVC–cyclohexanone solution during dissolution of the polymer. Final concentration of the solution was 0.5–1.0 g/100 cm 3 and the measurements were made at temperatures of 313, 333, 353, and 373 K. It was found that at 353 K, a temperature close to the glass transition temperature of PVC, the curve describing changes of viscosity vs. the dissolution time has a pronounced maximum. It follows from a preliminary analysis of the obtained results that this maximum corresponds to the viscosity of a PVC solution in which average apparent mass is many times larger than true average molecular mass of the studied sample. It mans that into the solution enter single chains and some formations, called microdomains in the literature, that are composed of tens of macromolecules. The microdomains disintegrate later to single macromolecules.