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Copolymerization of alkyl methacrylates with triallyl cyanurate. Determination of monomer reactivity ratios
Author(s) -
Ryttel Anna
Publication year - 1991
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1991.070420601
Subject(s) - reactivity (psychology) , methacrylate , copolymer , monomer , alkyl , polymer chemistry , chemistry , materials science , organic chemistry , polymer , medicine , alternative medicine , pathology
The free‐radical copolymerization of propyl, pentyl, hexyl, heptyl, octyl, and dodecyl methacrylates with triallyl cyanurate was investigated. The reactivity ratios were determined using the methods of Fineman‐Ross and Kelen‐Tüdös. The Alfrey‐Price Q and e values for the methacrylates were also evaluated. The effect of the length of alkyl group in methacrylates on reactivity ratios is discussed.