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A comparison of chemorheological models for thermoset cure
Author(s) -
Mijović Jovan,
Lee Chee Hung
Publication year - 1989
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1989.070381201
Subject(s) - thermosetting polymer , diglycidyl ether , epoxy , curing (chemistry) , materials science , isothermal process , diamine , branching (polymer chemistry) , phenomenological model , viscosity , thermodynamics , bisphenol a , polymer chemistry , polymer science , composite material , mathematics , physics , statistics
A chemorheological study of a thermoset system consisting of diglycidyl ether of bisphenol‐A (DGEBA) epoxy resin and a mixture of two armoatic amine curing agents; 4,4′ methylenedianiline (MDA) and m ‐phenylene diamine ( m ‐PDA), was conducted. Experimentally obtained viscosity data were checked against the predictions of two different viscosity models; one based on a phenomenological equation obtained by modification of the classical Williams–Landel–Ferry (WLF) equation and the other based on an extension of the branching theory originally proposed by Flory. In general, the predictions of both models were in excellent agreement with experimentally obtained isothermal and dynamic viscosity data. The branching theory model was found to have a slight advantage over the phenomenological equation model in describing the viscosity prior to gelation in a fast heating cure cycle.