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Interpenetrating polymer networks of polyurethane and polystyrene ionomers
Author(s) -
Hsieh K. H.,
Chou L. M.
Publication year - 1989
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1989.070380405
Subject(s) - polyurethane , materials science , polystyrene , ionomer , interpenetrating polymer network , polymerization , polymer , acrylic acid , polymer chemistry , scanning electron microscope , polymer blend , prepolymer , chemical engineering , composite material , copolymer , engineering
Interpenetrating polymer networks (IPNs) and linear blends of polyurethane (PUN) and poly(styrene–acrylic acid) (PSAA), which contain mutually opposite charge groups, i.e., tertiary amine and carboxyl groups, respectively, were synthesized through simultaneous bulk polymerization. Physical and mechanical properties of these IPNs and linear blends are discussed in the present paper. The tensile strength of both PUN/PSAA IPNs and linear blends has shown to increase with an increase of acrylic acid (AA) content in PSAA in any PUN/PSAA composition. A maximum value emerged in both polymer systems with 30 mol % AA in PSAA and the PUN/PSAA ratio of 25/75. A minimum swelling ratio as well as a maximum density was also observed in the IPNs and linear blends, respectively, related to this PUN/PSAA ratio. From dynamic mechanical analysis, two distinct relaxation transitions for the IPN or linear blend without AA in the system have merged into a single broad transition as the AA was introduced into PSAA. Two‐Phase morphology was observed from scanning electron microscopy studies for the polymer systems in the absence of charge groups; however, one‐phase morphology was observed when the charge groups were introduced.