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Dependence of viscoelastic properties on segregation degree of components in interpenetrating polymer networks
Author(s) -
Lipatov Yu. S.,
Rosovizky V. F.,
Datsko P. V.,
Maslak Yu. V.
Publication year - 1988
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1988.070360515
Subject(s) - materials science , polyurethane , degree (music) , composite material , viscoelasticity , polymer , moduli , interpenetrating polymer network , elastic modulus , curing (chemistry) , acrylate , dissipation factor , dynamic mechanical analysis , relaxation (psychology) , phase (matter) , copolymer , chemistry , physics , psychology , social psychology , optoelectronics , quantum mechanics , acoustics , dielectric , organic chemistry
The temperature dependences of elastic moduli, loss moduli, and mechanical loss angle tangent were investigated for the interpenetrating polymer networks: polyurethane–polyurethane acrylate by the method of dynamic mechanical spectroscopy (DMS). The segregation degree of components due to phase separation have been calculated from the parameters of relaxation maxima. An essential change was found in the segregation degree of components with the curing sequence of individual networks being changed. It was shown that, with the conditions and sequence of IPN formation changed, the phase separation degree can be fixed at a particular stage, i.e., the structures with a different segregation degree of components are obtainable. For the IPNs under investigation the variation of elastic moduli of the composites proved possible by fixing the separation degree of components.