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13 C‐NMR characterization of poly(1,5‐hexadiene)
Author(s) -
Cheng H. N.,
Khasat N. P.
Publication year - 1988
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1988.070350321
Subject(s) - characterization (materials science) , methylene , materials science , polymer , polymer chemistry , carbon 13 nmr , chemistry , stereochemistry , organic chemistry , nanotechnology , composite material
Poly(1,5‐hexadiene) was prepared and its structure characterized by high‐field 13 C nuclear magnetic resonance. The polymer was shown to contain repeating five‐membered rings separated by methylene bridges, with both cis and trans placements present in a 54 : 46 ratio. The result is compatible with the Marvel‐Garrison two‐step reaction mechanism.