Premium
13 C‐NMR characterization of poly(1,5‐hexadiene)
Author(s) -
Cheng H. N.,
Khasat N. P.
Publication year - 1988
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1988.070350321
Subject(s) - characterization (materials science) , methylene , materials science , polymer , polymer chemistry , carbon 13 nmr , chemistry , stereochemistry , organic chemistry , nanotechnology , composite material
Poly(1,5‐hexadiene) was prepared and its structure characterized by high‐field 13 C nuclear magnetic resonance. The polymer was shown to contain repeating five‐membered rings separated by methylene bridges, with both cis and trans placements present in a 54 : 46 ratio. The result is compatible with the Marvel‐Garrison two‐step reaction mechanism.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom