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Thioxanthone derivatives as photoinitiators in micelle photopolymerization
Author(s) -
Fouassier JeanPierre,
Lougnot DanielJoseph
Publication year - 1987
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1987.070340203
Subject(s) - photopolymer , thioxanthone , micelle , monomer , sodium dodecyl sulfate , photoinitiator , photochemistry , chemistry , reaction rate constant , absorption (acoustics) , polymer chemistry , organic chemistry , materials science , kinetics , polymer , aqueous solution , physics , composite material , quantum mechanics
This paper provides a complete survey of the primary processes involved in typical oil‐and water‐soluble thioxanthane derivatives dissolved in sodium dodecyl sulfate micelles, in the presence of monomers and amines. Special emphasis is laid on the determination of the rate constants of the different processes and the absorption spectra of the transients. Relevant data are shown and discussed with reference to the effectiveness of these molecules as photopolymerization initiators.