Premium
Amide derivatives of poly(3,4‐dimethylenepyrrolidine): Synthesis, characterization, and complexation studies
Author(s) -
Mathias Lon J.,
Vaidya Rajeev A.,
Halley Robert J.
Publication year - 1987
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1987.070330409
Subject(s) - formamide , acetamide , amide , polymer , polyelectrolyte , polymer chemistry , amine gas treating , chemistry , polyamide , surface modification , materials science , organic chemistry
Abstract Improved synthesis of polydiallylamine provides ready access to an entire family of amide‐functionalized polymers. Complete conversion to the acetamide derivative was attained under mild conditions. Formation of the formamide polymer required harsher conditions and did not give complete functionalization. The formamide polymer displayed typical polyelectrolyte behavior caused by residual amine units. Complexation with iodine and transition metal cations was strong as shown by UV, IR, and 13 C‐NMR evidence indicating potential of these polymers for trace metal recovery, waste water treatment, and antiseptic formulations.