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Effect of fillers on the compatibility of polymer blends
Author(s) -
Kalfoglou Nikos K.
Publication year - 1986
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1986.070320601
Subject(s) - materials science , composite material , talc , compatibility (geochemistry) , composite number , polyurethane , copolymer , filler (materials) , vinyl chloride , dynamic mechanical analysis , polymer , polymer blend , carbon black , natural rubber
The effects of carbon black, talc, and ultrafine silica filler, at different filler, loading, on the compatibility of two binary blends was examined. These were, the mechanically compatible polyurethane (PU)/poly(vinyl chloride) (PVC) at 25/75 weight ratio, and the poly(ε‐caprolactone) (PCL)/styrene–acylonitrile (SAN) copolymer (with 30% AN content), at the 50/50 blend composition. For the former system, both dynamic mechanical analysis (DMA) and DSC measurements indicated that, depending on the filler surface, boundary layers are formed at the filler–matrix interface shifting the PU relaxation to higher temperatures. No significant effect was observed for the PVC component. Though the mechanical spectra are also affected, essentially no T g shifts were observed for the PCL–SAN system. A qualitative explanation of selective filler activity towards the blend components was given by invoking the matrix–filler basic–acidic nature. Overall, the fillers had no compatibilizing effect on the blend. Using available theory both DSC and the DMA techniques agree in their estimate of the boundary layer thickness. Moduli data were also analyzed using mechanics models proposed for composite systems.