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Cyanoethylated cellulose prepared by homogeneous reaction in paraformaldehyde‐DMSO system
Author(s) -
Morooka Toshiro,
Norimoto Misato,
Yamada Tadashi
Publication year - 1986
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1986.070320217
Subject(s) - cellulose , paraformaldehyde , materials science , polymer chemistry , ultimate tensile strength , homogeneous , chemistry , organic chemistry , composite material , physics , thermodynamics
A series of cyanoethylated celluloses with various degrees of substitution was prepared by homogeneous reaction of cellulose in PF/DMSO system. Their thermal deformation properties changed regularly with the degree of cyanoethylation. By comparing highly cyanoethylated cellulose in the series with that prepared by a traditional cyanoethylation method, it was seen that they were quite different in physical properties such as thermal deformation or tensile properties. Based on the results of dynamic mechanical measurements and infrared spectroscopy, cyanoethylated cellulose prepared in PF/DMSO system was found to be a new cellulose derivative, which includes oligo‐oxymethylene groups at the position between the glucopyraneose ring and the cyanoethyl group in the side chain. The maximum DS value of this cyanoethylated cellulose was estimated to be ca. 2.5.