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Molecular weight distribution control in a semibatch “living” anionic polymerization. I. Theoretical study
Author(s) -
Couso D. A.,
Alassia L. M.,
Meira G. R.
Publication year - 1985
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1985.070300810
Subject(s) - monomer , reagent , molar mass distribution , homogeneous , polymerization , living anionic polymerization , volume (thermodynamics) , chemistry , chemical engineering , polymer chemistry , anionic addition polymerization , thermodynamics , organic chemistry , polymer , physics , engineering
A method to produce homopolymers of preestablished molecular weight distribution (MWD), through “living” anionic polymerizations carried out in homogeneous semibatch reactors is proposed and theoretically justified. In the direct form of the technique, very fast reactions are assumed, and the monomer and “killing” agent feed flows are obtained from the knowledge of the desired MWD, the system spreading function, the total reaction time, the initial reaction volume, and the reagent concentrations. Alternatively, by controlling a reactor outlet flow instead of the “killing” agent feed, an external deactivation of the “living” ends can be implemented. The method can be extended to slow reactions, to more elaborated mechanisms, and to take into account the unwanted deactivation of “living” ends by impurities in the monomer solution feed.