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Solubility of nonpolar and slightly polar organic compounds in low‐density polyethylene by inverse gas chromatography with open tubular column
Author(s) -
Tseng HsiaoShow,
Lloyd Douglas R.,
Ward T. C.
Publication year - 1985
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1985.070300503
Subject(s) - inverse gas chromatography , low density polyethylene , solubility , polyethylene , polar , chromatography , gas chromatography , hildebrand solubility parameter , materials science , inverse , chemistry , analytical chemistry (journal) , organic chemistry , physics , geometry , mathematics , astronomy
Inverse gas chromatography (IGC) with open tubular column was used to determine low pressure solubilities of 13 organic solutes in low‐density polyethylene (LDPE) for temperatures from 50 to 175°C. Based on the principle of corresponding states, two simple correlation equations were developed for estimation of the solubility of nonpolar and slightly polar solutes in rubbery and molten LDPE.