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Syntheses and properties of urethane prepolymers and their corresponding crosslinked films
Author(s) -
Yang ChinPing,
Wu WenLin
Publication year - 1983
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1983.070280806
Subject(s) - polypropylene glycol , polyurethane , materials science , isocyanate , prepolymer , glass transition , polyethylene glycol , polypropylene , toluene diisocyanate , peg ratio , molar ratio , elongation , polymer chemistry , ultimate tensile strength , composite material , polymer , chemistry , organic chemistry , catalysis , finance , economics
Trimethylol propane (TMP), polyglycol (PG), and toluene diisocyanate (TDI) were reacted in various molar ratios to produce TMP–TDI–PG–urethane prepolymers and then mixed with equivalent isocyanate generator (Desmodur AP‐Stable) in a mixture of m ‐cresol and naphtha to give polyurethane varnishes which finally became crosslinked films by the casting method. The mechanical properties and viscoelasticities of the PG‐modified and PG‐free polyurethane crosslinked films and the practicability of magnet wires coated with them were studied in this article. Three different PGs used in this experiment were polyethylene glycol, PEG(#400), polypropylene glycols, PPG(#1000) and PPG(#2000). In the case of adding PEG(#400) for modification, strength at break increased but elongation did not change. Meanwhile, glass transition temperature ( T g ) shifted to lower temperature with increasing molar ratio. In the case of adding PPG(#1000) and PPG(#2000) for modification, the samples changed their mechanical properties from hard and brittle to soft and tough. With increasing molar ratios, strength at break initially increased and then decreased gradually, and elongation varied a lot and was consistently contrary to strength at break. T g occurred at two regions: one at high temperature above 100°C for small molar ratios and the other at low temperature below 100°C for high molar ratios. Besides, for all PG‐modified polyurethane crosslinked films, strength at break showed a local maximum at TMP/TDI/PG = 1/1/0.5, which indicated their homogeneous structures. The molar ratios of PG‐modified urethane prepolymers, which are suitable for manufacturing practical magnet wires according to testing method JIS‐C‐3211, are as follows: TMP/TDI/PPG(#100) = 1/1/0.15–0.35 and TMP/TDI/PPG(#2000) = 1/1/0.10. PEG(#400)‐modified magnet wires were not accepted on the aging test. The properties of crosslinked films of practical magnet wires are generally as follows: strength at break at 200–700 kg/cm 2 , elongation less than 41%, and T g at 100–200°C.