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Effect of stirring on cellulose graft copolymerization
Author(s) -
Graczyk T.,
Hornof V.
Publication year - 1983
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1983.070280411
Subject(s) - copolymer , monomer , polymer chemistry , materials science , styrene , polymer , solubility , dissolution , methyl methacrylate , cellulose , methacrylate , xanthate , chemical engineering , chemistry , organic chemistry , composite material , engineering
Dissolving pulp was grafted with several monomers ranging from hydrophilic (dimethylaminoethyl methacrylate) to hydrophobic (styrene). The conversion of these monomers to polymer and copolymer was investigated in dependence on the number of revolutions of the agitator. The formation of grafted copolymer was found to be strongly influenced by stirring. For all the monomers employed, almost no copolymer was formed above 400 rpm. The formation of homopolymer was also severely reduced at higher stirring speeds. For some monomers, a maximum was obtained at about 200–300 rpm with both copolymer and homopolymer yields dropping off sharply at both lower and higher stirring speeds. The position of this maximum was affected by the size of the reactor. The behavior displayed by the xanthateFe 2+ –H 2 O 2 , Fe 2+ –H 2 O 2 , and ceric ion initiation systems was very similar. Also, monomer solubility in water seemed to have little importance in determining the general behavior.