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Study on triazine thiols. IV. Action of triazine thiols and their metal salts to peroxide
Author(s) -
Mori Kunio,
Nakamura Yoshiro
Publication year - 1983
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1983.070280223
Subject(s) - triazine , chemistry , epichlorohydrin , peroxide , zinc , copper , sulfur , polymer chemistry , decomposition , metal , organic chemistry , hydrogen peroxide , 1,3,5 triazine
Decomposition of t ‐butylhydroperoxide was retarded by triazine thiols and their zinc salts, but accelerated by the copper salts of triazine thiols as well as sulfur compounds such as dithiocarbamates and mercaptobenzothiazolates. Triazine thiols and their zine salts are effective antioxidants for polyethylene crosslinked with peroxide and containing copper, and for protecting epichlorohydrin vulcanizates against attack by “sour” or hydroperoxide‐containing gasoline.