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Structure–property relationships in PVC compression moldings
Author(s) -
Gilbert M.,
Ansari K. E.
Publication year - 1982
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1982.070270724
Subject(s) - materials science , crystallinity , composite material , annealing (glass) , ultimate tensile strength , fusion , crystallization , recrystallization (geology) , extrusion , rheometry , compression (physics) , rheology , chemical engineering , paleontology , philosophy , linguistics , engineering , biology
Compression moldings were produced from two rigid PVC compounds at a range of temperatures. The tensile and impact properties of these moldings depended primarily on the level of particle fusion as assessed by extrusion rheometry. Properties were not related to the level of primary crystallization measured by X‐ray diffraction, but the particle fusion process appears to be at least partly due to recrystallization. Fusion occurred more readily in the mass PVC compound than in the suspension PVC compound. Annealing the sheet produced at 200°C caused changes in crystallinity which resulted in small property changes. The maximum annealing effect occurred at 110°C.