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Crystallinity and heats of crystallization of cellulose: A microcalorimetric investigation
Author(s) -
Dale Bruce E.,
Tsao George T.
Publication year - 1982
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1982.070270412
Subject(s) - crystallization , cellulose , enthalpy , dissolution , exothermic reaction , crystallinity , solvent , exothermic process , materials science , chemistry , polymer chemistry , thermodynamics , organic chemistry , crystallography , adsorption , physics
We have used a sensitive adiabatic microcalorimeter to study cellulose dissolution in its metal complex solvents cadoxen and ferric sodium tartrate (FeTNa). Heats of crystallization of cellulose I and II have thereby been estimated and range from −4.07 kcal/mol to −5.43 kcal/mol. A solvent‐dependent heat of reaction factor has been invoked to explain differences in the heats of crystallization obtained by the two solvents. Conversion of cellulose I to cellulose II is an exothermic process with an enthalpy change of about −6.0 cal/g cellulose. The crystallinities of various cellulose samples have been determined using these thermodynamic data and have been found to be generally consistent with values given by more traditional means.