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Photooxidation of the surfaces of polyphenylene oxide and polysulfone
Author(s) -
Peeling James,
Clark David T.
Publication year - 1981
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1981.070261122
Subject(s) - polysulfone , stoichiometry , oxygen , oxide , chemistry , sulfone , photochemistry , degradation (telecommunications) , carbon fibers , sulfur , radical , irradiation , polymer chemistry , reaction mechanism , polymer , catalysis , organic chemistry , materials science , computer science , nuclear physics , composite material , telecommunications , physics , composite number
Changes in the composition and structure of the surfaces of polyphenylene oxide (PPO) and polysulfone caused by UV photooxidation are followed using ESCA. The surface stoichiometry of PPO changes from C 8 O 1 to C 8 O 4.8 on photooxidation, the oxygen being added in the form of carbonyl and especially carboxyl groups. Surface photooxidation is rapid, the ESCA spectra showing substantial changes after a few minutes of irradiation, and no further changes being detected after 10 h of reaction. The surface photooxidation of polysulfone occurs in three stages. In the first 2 h rapid oxidation takes place at carbon atoms, the levels of C—O, carbonyl, and carboxyl groups increasing at comparable rates. This is followed by slower oxygen incorporation up to 15 h of reaction, during which time carbonyl and carboxyl levels increase and oxidation of the sulfone sulfur is observed. Some degradation occurs as groups containing carbon and oxygen are lost from the surface. Further oxidation then produces a decrease in the surface levels of C—O and carbonyl groups, and further degradation. The photooxidized surface has a stoichiometry of C 10 O 6 S, compared with C 27 O 4 S in the unreacted polymer.