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On shift and resolution of relaxation maxima in two‐phase polymeric systems
Author(s) -
Lipatov Yu. S.,
Rosovitsky V. F.,
Babich B. V.,
Kvitka N. A.
Publication year - 1980
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1980.070250605
Subject(s) - viscoelasticity , glass transition , materials science , polymer , maxima , relaxation (psychology) , phase (matter) , phase boundary , shear modulus , phase transition , thermodynamics , modulus , composite material , chemistry , physics , social psychology , psychology , organic chemistry , performance art , art history , art
The results of calculations of viscoelastic properties of filled polymers assuming “boundary layer” and the polymer matrix having their own and different glass transition temperatures are presented. The calculations have been made on the basis of the models in series and parallel coupling of viscoelastic bodies as well as Takayanagi's model. Using specified temperature, dependences of viscoelastic properties of the polymer and the “boundary layer” temperature dependences of the real part G′ of the complex shear modulus and tan δ for such a two‐phase system with varied differences in glass transition temperatures and concentration of the components were derived. The degree of maxima shift observed experimentally for the filled polymer owing to variation of properties of the “boundary layer” (its concentration and glass transition temperature) were evaluated. Conditions for the appearance of two maxima tan δ for the respective glass transtion temperatures of the polymer and “boundary layer” on the curves tan δ = f ( T ) were determined.