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Effect of nitrogen‐donor ligands on the stability of the photolysis products of Mn 2 (CO) 10
Author(s) -
Busetto C.,
Mattucci A. M.,
Cernia E.
Publication year - 1980
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1980.070250306
Subject(s) - disproportionation , photodissociation , nitrogen , ligand (biochemistry) , chemistry , solvent , inorganic chemistry , photochemistry , ion , polymer chemistry , catalysis , organic chemistry , biochemistry , receptor
The photolysis of Mn 2 (CO) 10 in the presence of nitrogen donor ligands has been investigated in various solvents. The disproportionation reaction has been found to be strongly dependent on the solvent and on the temperature. The substitution of CO with the nitrogen donor ligand takes place on the anion Mn(CO) − 5 . The polymeric ligand poly(4‐vinylpyridine) manifests a stabilizing effect on the substitution product.