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Thermodynamics of gas solubilities in molten polymers
Author(s) -
Liu D. D.,
Prausnitz J. M.
Publication year - 1979
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1979.070240310
Subject(s) - supercritical fluid , polymer , thermodynamics , polyethylene , materials science , siloxane , chemistry , organic chemistry , physics
Perturbed‐hard‐chain theory is extended to mixtures of polymers and volatile fluids, including supercritical gases. This extension is used to derive an expression for Henry's constant for a solute in a molten polymer. Theoretical calculations and data reduction are reported for a variety of solutes in polyethylene, polyisobutylene, and poly(dimethyl siloxane) in the temperature region 25–300°C. Calculated Henry's constants and their temperature dependence are generally in good agreement with the limited experimental data now available.