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The effect of thermal history and strain rate on the mechanical properties of diethylenetriamine‐cured bisphenol‐A‐diglycidyl ether epoxies
Author(s) -
Morgan Roger J.
Publication year - 1979
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1979.070230916
Subject(s) - diglycidyl ether , epoxy , materials science , diethylenetriamine , composite material , ultimate tensile strength , thermosetting polymer , strain rate , elongation , bisphenol a , polymer chemistry
The tensile mechanical properties of diethylenetriamine (DETA)‐cured bisphenol‐A‐diglycidyl ether (DGEBA) epoxies prepared from 9, 11 and 13 phr DETA are reported as a function of thermal history, strain‐rate and test temperature. These epoxies exhibit macroscopic yield stresses and >10% ultimate elongations. The mechanical properties of these epoxies exhibit a free‐volume dependence as a function of thermal history. Annealing below T g causes an increase in the macroscopic yield stress and a decrease in the ultimate elongation, whereas quenching from above T g lowers the yield stress and increases the elongation. These mechanical property modifications are shown to be reversible with reversible thermal–anneal cycles. The activation volumes associated with Eyring's theory for stress‐activated viscous flow for the DGEBA‐DETA epoxies are within the range of values (9–12 nm 3 ) reported for noncrosslinked polymers. These observations suggest that the DGEBA‐DETA epoxies are not as highly crosslinked as would be expected from normal addition reactions of epoxide groups with primary and secondary amines. The formation of lower crosslink density networks is discussed in terms of potential chemical reactions.