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Copolymers of 3,3′,4,4′‐tetraaminobiphenyl and 1,2,4,5‐tetraaminobenzene with 1,1′‐bis(glyoxalyl)‐ferrocene and 1,1′‐bis(phenylglyoxalyl)ferrocene
Author(s) -
Vernois Michel,
Williams H. Leverne
Publication year - 1979
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1979.070230603
Subject(s) - ferrocene , copolymer , polymer , monomer , triclinic crystal system , materials science , polymer chemistry , metallocene , ferromagnetism , polymer science , polymerization , chemistry , crystal structure , crystallography , composite material , electrochemistry , electrode , physics , quantum mechanics
Four monomers were synthesized and four copolymers prepared. The polymers were dark‐colored, poorly soluble, crystalline products. The x‐ray photographs were typical of triclinic crystals. The polymers degraded at temperatures lower than those characteristic of the analogous homopolymers. The recovered polymers were ferromagnetic.