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Thermodynamic interpretation of solute–polymer interactions at infinite dilution
Author(s) -
Karim Khalid A.,
Bonner David C.
Publication year - 1978
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/app.1978.070220510
Subject(s) - dilution , polarizability , enthalpy , thermodynamics , enthalpy change of solution , polymer , dipole , hydrogen bond , methacrylate , atmospheric temperature range , materials science , chemistry , organic chemistry , molecule , physics , copolymer
Heats of solution at infinite dilution of solutes in poly(ethyl methacrylate) were estimated using gas–liquid chromatography over a temperature range of 417.74 K–427.55 K. The heat of solution is related to solute polarizability and dipole moment. Contributions of specific interactions such as hydrogen bonding and charge‐transfer complexing to the enthalpy of solution were also determined.